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$B8&5fFbMF!&@.2L(B | $B-!I9$N??6u;g308wJ,2rH?1~$H@14V2=3X(B $B??6u;g308w$dEE;R@~$K$h$kI9J,2rH?1~$N8&5f$O!"J,;R1@$d@14V?P$G$N2=3XH?1~2aDx$rM}2r$9$k>e$G=EMW$G$"$k!#$3$l$^$G$N8&5f$G0J2<$NH?1~$,3NG'$5$l$F$$$?!#(B $B!!(BH2O(ice) + h$B&M(B/e-$B!!!a!!(BH + OH (1) $B!!(BH + H$B!!!a(B H2 ∆H = -4.5 eV (2) $B!!(BH + H2O $B!a!!(BH2 + OH ∆H = 0.6 eV (3) $B!!(BOH + OH $B!a!!(BH2O2 (4) $B>e5-H?1~2aDx$K$*$$$FJ|=P$5$l$?86;R!&J,;R$O5$Aj2=3XH?1~$r5/$3$9$,!"$=$NH?1~B.EY$O1?F0!&FbIt%(%M%k%.!<$K$h$jBg$-$/B%?J$5$l$k>l9g$,$"$k!#(B $B$?$H$($P!"(B $B!!(BH2 + O(3P) $B!a!!(BOH + H (5) $B$NH?1~$K$*$$$F!"(BH2(v=3)$B$NH?1~B.EYDj?t$O(BH2(v=0)$B$N(B11$B>hG\$bBg$-$/$J$k$HJs9p$5$l$F$$$k!#$^$?(BH2O2$B@8@.H?1~$O(BOH$B%i%8%+%k$N:F7k9gH?1~(B(4)$B$G$"$k$H9M$($i$l$F$$$k$,$=$NI9>eFbIt$K$*$1$kH?1~%@%$%J%_%/%9%rL@$i$+$K$7$?!#(B $B-"I9$K5[Ce$7$?(BNOx$B$N;g308wJ,2r$HBg5$2=3X(B $B!!6K0hBg5$2=3X$G$OCOI=$NI9I=LL$K(BHNO3$B$,5[Ce$9$k$H%$%*%s2=$7!"(BNO3-$B$K$J$k!#(BNO3-$B$OCOI=$KFO$/(B300-350nm$B$N;g308w$G$b5[<}$,$"$k$?$a8wJ,2rH?1~$r5/$3$7!"Bg5$2=3X$K$H$C$F=EMW$J%i%8%+%k$G$"$k(BOH$B$r@8@.$9$k!#(B $B!!(BHNO3 $B!a!!(B H+ + NO3- (6) $B!!(BNO3- + h$B&M(B $B!a(B NO2 + O- (7) $B!!(BO- + H+ $B!a(B OH (8) $B$7$+$7$J$,$i(BNO3-$B$N8wJ,2r$K$h$kBg5$$X$N(BOH$BJ|=P%a%+%K%:%`$OL@$i$+$K$O$J$C$F$$$J$$!#$3$NE@$rL@$i$+$K$9$k$?$aI9I=LL$N8wH?1~$K$h$k@8@.J*$N@8@.%a%+%K%:%`!"$J$i$S$K1?F0!&FbIt%(%M%k%.!<$K4X$9$k8&5f$r9T$C$?!#(B |
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$B@.2L$H$J$kO@J8!&3X2qH/I=Ey(B |
A. Yabushita$B!$(B T. Hama$B!$(B M. Yokoyama$B!$(B M. Kawasaki$B!$(B S. Andersson$B!$(B . N. Dixon$B!$(B M. N. R. Ashfold$B!$(B N. Watanabe$B!$(BTranslational and rotational energy measurements of photodesorbed water olecule in the vibrational ground state from amorphous solid water$B!$(B strophys. J. Lett.$B!$(B 699$B!$(B L80-83 (2009) T. Hama$B!$(B A. Yabushita$B!$(B M. Yokoyama$B!$(B M. Kawasaki$B!$(B N.Watanabe$B!$(BFormation mechanisms of oxygen atoms in the O(3PJ) state from the 157 nm photoirradiation of amorphous water ice at 90 K$B!$(B J. Chem. Phys.$B!$(B in press |
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